Binding and activation of small molecules by a quintuply bonded chromium dimer.
نویسندگان
چکیده
The quintuply bonded [(H)L(iPr)Cr]2 reacts with various small molecules, revealing a pattern of two kinds of transformations. Unsaturated molecules that are neither polar nor oxidizing form binuclear [2+n] cycloaddition products retaining Cr-Cr quadruple bonds. In contrast, polar or oxidizing molecules effect the complete cleavage of the Cr-Cr bond.
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عنوان ژورنال:
- Chemical communications
دوره 50 20 شماره
صفحات -
تاریخ انتشار 2014